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Chlorure de chromyle, 99,99 % (à base de métaux), Thermo Scientific Chemicals

37.27€ - 374.87€

Identifiants chimiques

CAS 14977-61-8
Formule moléculaire Cl2CrH4O2
Poids moléculaire (g/mol) 158.926
Numéro MDL MFCD00010951
Clé InChI HOCPFYCTFLRIAK-UHFFFAOYSA-L
Synonyme chromyl chloride
CID PubChem 101943071
Nom IUPAC chrome(2+);dichlorure;dihydrate
SMILES O.O.[Cl-].[Cl-].[Cr+2]
Consulter d'autres spécifications

Produits 3
Code produit Marque Quantité Prix Quantité et disponibilité  
Code produit Marque Quantité Prix Quantité et disponibilité  
11318508
Afficher les documents Détails de la promotion
Thermo Scientific Alfa Aesar
040517.04
2 g Cet article est supprimé, vous trouverez le remplacement et les alternatives dans les onglets respectifs ci-dessous s'ils ont été identifiés
N/A
11398498
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Thermo Scientific Alfa Aesar
040517.09
10 g
107.54€
10g
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11308508
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Thermo Scientific Alfa Aesar
040517.18
50 g
374.87€
50g
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Description

Description

Highly spin-polarized chromium dioxide (CrO2) thin films were deposited on 100 TiO2 substrates by chemical vapor deposition using chromyl chloride as a precursor. Chromyl chloride (Cr02C12) reacts with cyclohexane solvent at 75 OC to give a dark precipitate along with chlorocyclohexane and a small amount of cyclohexene (in 10.0 and ca. 0.3% yields based on chromium). Chromyl chloride, CrO2C12, oxidizes cyclooctane, isobutane, and toluene under mild conditions (25-60 C). The reactions give chlorinated products (chlorocyclooctane, tert- butyl chloride, and benzyl chloride) and a dark chromium-containing precipitate. Used for Organic oxidations and chlorination, chromium coordination complexes, catalyst for polymerization of olefins. Chromyl chloride in carbon tetrachloride solution reacts in the cold with cyclohexene, cyclopentene, and 1-hexene to give the various isomeric chlorohydrins as the major products.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

  • Javellisation et oxydation organique, complexes de coordination du chrome, catalyseur pour la polymérisation des oléfines
Spécification

Identifiants chimiques

14977-61-8
158.926
HOCPFYCTFLRIAK-UHFFFAOYSA-L
101943071
O.O.[Cl-].[Cl-].[Cr+2]
Cl2CrH4O2
MFCD00010951
chromyl chloride
chrome(2+);dichlorure;dihydrate

Spécification

117°C
-96.5°C
Liquide
Cl2CrH4O2
UN1758
chromyl chloride
O.O.[Cl-].[Cl-].[Cr+2]
158.926
154.9
Pungent, makes eyes water
1.911g/mL
Chromyl chloride
14977-61-8
(Base des métaux)
MFCD00010951
14,2248
HOCPFYCTFLRIAK-UHFFFAOYSA-L
chrome(2+);dichlorure;dihydrate
101943071
99.99%
Moisture Sensitive
Vidéos
Sécurité et traitement

Sécurité et traitement

GHS H Statement
H272-H340-H350-H314-H318-H317
May intensify fire
oxidizer.
May cause genetic defects.
May cause cancer.
Causes severe skin burns and eye damage.
Causes serious eye damage.
May cause an allergic skin reaction.

GHS P Statement
P221-P210-P303+P361+P353-P305+P351+P338-P405-P501a
Take any precaution to avoid mixing with combustibles.
Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do.
Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: I; Proper Shipping Name: CHROMIUM OXYCHLORIDE

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missing translation for 'tsca' : TSCA

FDS
Documents

Documents

Product Certifications

RUO – Research Use Only